not really technical, or complete, but still a list… anyways, I should clean up the formatting later.

flintstones cops: (check before episode 7 for others)
s01e07: handcuffed for pushing cop in pool after noise complaint
s01e12: booked on an 803 [attacking an old man with his own cane]
s01e17: Fred wishes for money, bag of cash falls on his head, cops think they are bank robbers
s01e18: A bunch of traffic tickets for a camper that came loose off the car
s01e19: Thought Fred was 88 Fingers Louie and arrested him for driving a stolen piano down the street
s02e27: Fred gets in trouble with the cops for trying to get a letter out of a mailbox
s03e11: Barney gets arrested for hassling ladies after sneaking Fred in to ball game on Ladies Day
s03e20: Fred gets in shit from cop because he stopped traffic to yell at Barney
              Fred gets pulled over for doing 55mph in 35mph zone
s03e23: Fred gets pulled over for speeding on the way to hospital when Wilma is pregnant
s03e24: Fred gets pulled over for speeding on the way back to hospital when Pebbles cried
              and again when he thinks the laundry pickup took Pebbles
s03e27: Swedish musicians are staying at Flintstone house and cops come for Barney's noise complaint
s04e04: Fred gets in shit with cops when Dino runs away and Fred steals the wrong dog
s04e05: Fred gets new glasses and accidentally gets in to a cop car
s04e06: Fred gets chased by cops while driving a bathtub
s04e11: Fred mistakenly gets in trouble with cops when he thinks Pebbles stole jewelry
s04e13: A cop swings Fred "over the bar" to teach him not to go on the kiddie swings
s04e13: Fred & Barney end up in jail for playing poker
s04e14: Get chased by cop for trying to break in to Bedrock Plaza hotel
s04e14: Fred accidentally lassos a cop when trying to pull down everyone's TV antennae
s04e21: Fred builds a room on the side of their house, turns out it is over the property line and they
              fight - Fred unknowingly chokes a cop throgh the little hole in the wall between halves
s04e21: Fred gets chased (and shot at) by cops while dressed as Son Of Rockzilla
s05e04: Boulderettes get sent to Pebbles' birthday party and clown shows up at lodge party - cops get called
S06E11: Fred & Barney get arrested for fighting in the yard while dressed up as devils

flintstones jobs: (check before episode 8 for others)
s01e08: Fred loses job for twisting his boss' nose at dinosaur races
s01e13: Fred & Barney quit to open a drive-in restaurant
s01e15: No mention of regular job but fred went on tour for many weeks as Hi-Fi the singer
s01e22: Fred leaves job temporarily to acts as J.L. Gotrocks
s01e23: Does not say he left their jobs but they joined the army
s02e02: Cousin Tumbleweed buys Fred & Barney's companies so they can watch the ranch for a month
s02e03: Fred quits his job to become a school bus driver
s02e11: Fred gets fired for dropping a rock on his boss at work
s02e17: Fred quits work to manage Wilma's TV career
s02e27: Fred writes nastygram to Mr. Slate for not giving him his annual raise
        - Wilma saves him from actually getting fired
s03e02: Barney loses his job and ends up Fred's boss (Mr. Slate's nephew)
s03e22: Fred gets Barney to pose as employer in order to get Mr. Slate to give him a raise
        - Plan backfires and he gets fired instead
s04e16: Fred gets fired when an alien clone of him beats up Mr. Slate
s05e13: Fred gets fired when Mr. Slate finds out he skipped work to race a car as Goggle Pyzano
        - Then unfired when Mr. Slate tries to use Pyzano's popularity to get free advertising
s05e20: Fred almost gets fired for moonlighting as a Resident Stationary Engineer (janitor) at his new apartment

flintstones clubs: (check before episode 11 for others)
s01e11: Loyal Order Of Dinosaurs
s01e24: Loyal Order Of Water Buffalos are staying at Smoothie's hotel
s02e06: Fred says that he & Barney should get Rock Quary in to the Secret Order Of The Dinosaurs
s02e11: Fred has a meeting at the Loyal Brotherhood Of Water Buffalos (first time with the blue hat)
        - Leader referred to himself as "King Buffalo"
s02e24: Royal Order Of Water Buffalo
s03e06: Royal Order Of Water Buffalos (Wilma's wording)
s03e07: Loyal Order Of Water Buffalos (Wilma's calls leader "Mystic Imperial Poobah")
s03e18: Loyal Order Of Water Buffalos (taking nominations for "Grand Imperial Poobah")
        - Fred refers to "Exalted Poohbah"
s03e20: Loyal Order Of Water Buffalos
s04e13: Loyal Order Of Buffalos
s04e14: During Peek-a-boo Camera TV show the Imperial Grand Poobah calls and Fred has to put on his water buffalo hat
s04e21: Loyal Order Of Water Buffalos
s04e23: Water Buffalo Lodge & Grand Poobah

Flintstones addresses: (check before episode 17 for others)
s01e17: 345 Stone Cave Road
s01e27: Fred & Barney take the subway to Pebble Street
s02e09: Phone number at Flintstone house is Bedrock313
s02e15: Dino's vet sends Dino's x-rays to 35 Cobblestone Road
s03e09: Telegram office says address is on Cobblestone Lane
s03e16: Kissing Burglar is headed for 323 Cobblestone Lane
s04e05: Fred thinks he is losing his mind and keeps repeating his name and address of 222 Rock Way
S06E11: Cops send squad car to 342 Gavelpit Terrace

Notes:
s03e03: First time the Gay Old Time song and drive-in appeared in opening credits
s03e19: First time I heard a laugh track
s03e23: Pebbles is born
s04w03: BammBamm arrives
s04e10: Second time I heard a laugh track
s04e11: Strange new art style showed up
s04e17: Wilma's mother is referred to as Mrs. Slaghoople
s04e25: Wilma's mother is referred to as Mrs. Slaghoople
s05e01: Hopperoo AKA "Hoppy" is introduced